Synthesis Of Multinary Composite (nimncucos) Electrodes Aqueous Hybrid Supercapacitors

5 min read Jun 26, 2024
Synthesis Of Multinary Composite (nimncucos) Electrodes Aqueous Hybrid Supercapacitors

Synthesis of Multinary Composite (NiMnCuCoS) Electrodes for Aqueous Hybrid Supercapacitors


Supercapacitors have gained significant attention in recent years due to their high power density, long cycle life, and rapid charging/discharging capabilities. Among various types of supercapacitors, aqueous hybrid supercapacitors have emerged as a promising solution for energy storage applications. The development of high-performance electrodes is crucial for achieving excellent electrochemical performance in these devices. In this article, we will discuss the synthesis of multinary composite electrodes comprising nickel (Ni), manganese (Mn), copper (Cu), and cobalt (Co) sulfides (S) for aqueous hybrid supercapacitors.


Conventional supercapacitor electrodes are often composed of a single metal oxide or conductive material, which may limit their electrochemical performance. The development of multinary composite electrodes has shown promising results in improving the specific capacitance, rate capability, and cycling stability of supercapacitors. The incorporation of multiple metal sulfides with different redox properties can enhance the electrochemical performance of the electrodes.

Synthesis of NiMnCuCoS Electrodes

The synthesis of NiMnCuCoS electrodes involves a simple and cost-effective method, which can be achieved through a series of steps:

Step 1: Preparation of Precursors

NiCl2, MnCl2, CuCl2, and CoCl2 were used as precursor salts for the synthesis of NiMnCuCoS. These salts were dissolved in distilled water to form a homogeneous solution.

Step 2: Hydrothermal Synthesis

The precursor solution was then transferred to a Teflon-lined autoclave and subjected to hydrothermal synthesis at 180°C for 12 hours. During this process, the metal ions react with thioacetamide to form the corresponding metal sulfides.

Step 3: Calcination

The resulting precipitate was collected, washed, and calcined at 300°C for 2 hours to remove any impurities and improve the crystallinity of the material.

Step 4: Electrode Fabrication

The calcined NiMnCuCoS powder was mixed with conductive agents (e.g., carbon black) and binders (e.g., polyvinylidene fluoride) to form a uniform paste. The paste was then deposited onto a nickel foam current collector and dried at 80°C for 2 hours.

Characterization and Electrochemical Performance

The synthesized NiMnCuCoS electrodes were characterized using various techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The XRD pattern revealed a mixed phase of NiS, MnS, CuS, and CoS, indicating the successful formation of the multinary composite.

The electrochemical performance of the NiMnCuCoS electrodes was evaluated using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS) in a three-electrode configuration. The results showed a high specific capacitance of 1450 F/g at a scan rate of 5 mV/s, excellent rate capability, and stable cycling performance over 5000 cycles.


In conclusion, the synthesis of NiMnCuCoS electrodes for aqueous hybrid supercapacitors has been successfully demonstrated. The hydrothermal synthesis method provides a simple and cost-effective route for the preparation of multinary composite electrodes. The electrochemical performance of the NiMnCuCoS electrodes shows great promise for energy storage applications. Further optimization of the electrode composition and structure is expected to lead to even better electrochemical performance.

Future Directions

  • Investigation of the electrode material's composition and structure on its electrochemical performance
  • Development of advanced electrode architectures for improved energy storage and power delivery
  • Scale-up of the synthesis method for large-scale production of NiMnCuCoS electrodes